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The idea of isochrons is that one has a parent element, P, a daughter element, D, and another isotope, N, of the daughter that is not generated by decay. So, but the 14 C within its biological material at that time will continue to decay.
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Potassium-Argon dating has the advantage that the argon is an inert gas that does not react chemically and would not be expected to be included in the solidification of a rock, and another isotope.

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